文章基本信息

标题：A Modified Polymer from Polyacrylonitrile
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作者：Indra Bajaj ; S. R. Chatterjee
期刊名称：Defence Science Journal
印刷版ISSN：0976-464X
出版年度：2014
卷号：19
期号：3
页码：193-198
DOI：10.14429/dsj.19.7490
语种：English
出版社：Defence Scientific Information & Documentation Centre
摘要：Polyacrylonitrile has been modified by introducing thioamide groups (-CSNH/sub 2/) in place of nitride groups (-CN) in the chain by passing dry H/sub 2/ S gas through a 5% solution of the polymer in N-N dimethylformamide. The modified polymer is soluble in acetone. X-ray study revealed the complete loss of crystallinity in the modified polymer. Infra-red spectrum of the polymer film shows strong absorption bands at 3390 cm/sup 1/, 2273 cm/sup 1/ and 1667 cm/sup 1/ indicating the presence of both thioamide and nitride groups in the polymer chain.
关键词：Polymer chain;Crystallinity;X ray study;Thioamide groups