文章基本信息

标题：Stereospecific Synthesis of trans-t-Butyl Beta-Methyl-Beta-(p-Bromophenyl)-Glycidate and its Pyrolysis
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作者：R. K. Bansal ; K. Sethi
期刊名称：Defence Science Journal
印刷版ISSN：0976-464X
出版年度：2014
卷号：29
期号：4
页码：151-152
DOI：10.14429/dsj.29.6507
语种：English
出版社：Defence Scientific Information & Documentation Centre
摘要：trans-t-Butyl Beta-(p-bromophenyl)-glcidate has been synthesised by the stereospecific epoxidation of the unsaturated ester (V)using m-chloroperbenzoic acid. The trans-configuration was assigned on the basis of spectral analysis and comparison with the similar product obtained in the Darzens condensation. The ester on pyrolysis yields a-methyl a- (p-bromophenyl) acetaldehyde.
关键词：Darzens condensation;Chloroperbenzoic acid