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  • 标题:Polarographic Study of Cd-Schiff Base Complex
  • 本地全文:下载
  • 作者:M. S. Patel ; T. Trivedi ; D. N. Vyas
  • 期刊名称:Defence Science Journal
  • 印刷版ISSN:0976-464X
  • 出版年度:2014
  • 卷号:29
  • 期号:1
  • 页码:7-10
  • DOI:10.14429/dsj.29.6457
  • 语种:English
  • 出版社:Defence Scientific Information & Documentation Centre
  • 摘要:Polarographic behaviour of Cd/sup 2/+ with a schiff base salicyladehyde trisbuffer has been studied in DMF water media of three different compositions (viz., 0%, 30% and 50% v/v of DMF). Stability constant, free energy change delta G, enthalpy change delta H and entropy change delta S of the systems are calculated for all the three media at three different temperatures (viz., 30 degree centigrade, 40 degree centigrade and 50 degree centigrade). A relation of halfwave potential of the system with the dielectric constant of the medium has also been verified.
  • 关键词:Polarographic behaviour;DMF water media;Dielectric constant
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