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  • 标题:Graphite electrode modified with Indigo Carmine for Cu(II) ions detection
  • 本地全文:下载
  • 作者:Mariame Coulibaly ; Liana Maria Mureşan ; Ionel Cătălin Popescu
  • 期刊名称:E3S Web of Conferences
  • 印刷版ISSN:2267-1242
  • 电子版ISSN:2267-1242
  • 出版年度:2013
  • 卷号:1
  • 页码:1-3
  • DOI:10.1051/e3sconf/20130141035
  • 出版社:EDP Sciences
  • 摘要:An electrochemical method for Cu(II) determination, based on its reaction with indigo carmine (IC) in alkaline medium and differential pulse voltammetry performed at graphite electrode, was elaborated. The experimental parameters affecting the Cu(II) - IC complex formation (reaction time and pH) were optimized. The linear range of the calibration curve, obtaining by representing the IC oxidation current (Eappl = 0.175 V vs. Ag/AgCl,KClsat) versus the Cu(II) concentration (pH 10), was from 10 μM up to 70 μM Cu (II) and the detection limit was 4.74 μM.
  • 关键词:Cu(II); indigo carmine; differential pulse voltammetry
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