文章基本信息

标题：Synthesis, characterization and thermal degradation kinetics of Copolyesters ,
本地全文：下载
作者：Benarbia A. ; Elidrissi A. ; Ganetri I. 等
期刊名称：Journal of Materials and Environmental Science
印刷版ISSN：2028-2508
出版年度：2014
卷号：5
期号：4
页码：1262-1279
出版社：University of Mohammed Premier Oujda
摘要：The copolymer of lactic acid, ethylene glycol and succinic acid (cop1) was synthesized by the condensation process of lactic acid, succinic acid and ethylene glycol. The copolymer was then characterized by FTIR, 1 HNMR, 13 CNMR, DSC, TGA/DTA; the (cop1) was analyzed also for various properties such as acid value, number average molecular weight, etc. The thermal degradation kinetics was investigated for the (cop1) by dynamic thermogravimetry, in a nitrogen atmosphere, at the temperature range of 25 °C to 500 °C, at constant nominal heating rates of 10, 15 and 20 °C/min, respectively. Two distinct mass change stages in the thermogravimetric analysis curves indicated that the degradation of (cop1) may be attributed to two reactions. The Kissinger, Friedman and Flynn-Ozawa-Wall methods were developed, the corresponding activatio n energies, frequency factors and reaction orders of the two reactio ns were determined. We proposed the thermal degradation mechanism of the copolymer.
关键词：Biodegradable polymer; Thermal degradation; Thermogravimetry; Kinetic analysis.