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  • 标题:Immobilization of 60Co and 90Sr ions using red mud from aluminum industry
  • 本地全文:下载
  • 作者:Milenković Aleksandra S. ; Smičiklas Ivana D. ; Marković Jelena P.
  • 期刊名称:Nuclear Technology and Radiation Protection
  • 印刷版ISSN:1451-3994
  • 出版年度:2014
  • 卷号:29
  • 期号:1
  • 页码:79-87
  • DOI:10.2298/NTRP1401079M
  • 出版社:VINČA Institute of Nuclear Sciences
  • 摘要:

    The removal of 60Co and 90Sr from the aqueous phase was tested using red mud - the fine grained residue from bauxite ore processing. This industrial waste represents a mixture of numerous minerals, mainly oxides and hydroxides of Fe, Al, Si, and Ti. Experiments were conducted as a function of contact time, pH, and pollutant concentrations. Kinetic data were well fitted with a pseudo-second order equation. The calculated rate constants and initial sorption rates indicated faster sorption of Sr2+ ions. Removal of both cations rapidly increased with the initial pH increase from 2.5 to 3.5. With the further increase of pH, Co2+ sorption was nearly constant (98%-100%), whereas Sr2+ removal remained at the same level to initial pH ~8 and gradually increased to 100% at pH 12. Equilibrium sorption data followed the Langmuir model, with the maximum sorption capacities of 0.52 mmol/g for Co2+ and 0.31 mmol/g for Sr2+. Sorbed cations exhibited high stability in distilled water. Desorption of Co2+ was also negligible in the presence of the competing Ca2+ cation, while 42%-25% of Sr2+ ions were desorbed depending on the previously sorbed amount. The results indicate that red mud is of potential significance as Co2+ and Sr2+ immobilization agent due to its high efficiency, abundance, and low-cost. [Projekat Ministarstva nauke Republike Srbije, br. 43009]

  • 关键词:90Sr; 60Co; immobilization; red mud
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