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  • 标题:Synthesis and Anticorrosion for X70 Steel of Propynol Derivatives in Acid Medium,
  • 本地全文:下载
  • 作者:Yu Q. ; Jiang X. ; Zhou L.
  • 期刊名称:Journal of Materials and Environmental Science
  • 印刷版ISSN:2028-2508
  • 出版年度:2014
  • 卷号:5
  • 期号:1
  • 页码:13-32
  • 出版社:University of Mohammed Premier Oujda
  • 摘要:1-dodecyl/tetrdecyl/hexadecyl-3-(4-hydrox ybut-2-ynyl) p yridinium bromides (namely M-n) were synthesized and their inhibition capacity for X70 steel in 5 M HCl investigated by weight loss test, electrochemical methods and surface analysis technics. The results sho wed that M-n could efficiently protect X70 steel from corrosion with an efficiency of 99% at 40 M and 60 M in 5 M H Cl solution. The inhibitory efficiency was almost unchanged at 30-60 M for M-n at a concentration of 40 M. Surface morphology analysis evidenced the protective film of M-n on X70 steel surface. The adsorption of M-n obeyed the Langmuir adsorption isotherm. And it was a spontaneous, exothermic and entropy driving process
  • 关键词:X70 steel; Weight loss; EIS; Corrosion inhibitor; Intramolecular synergism
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