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标题：Detection of solar wind-produced water in irradiated rims on silicate minerals
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作者：John P. Bradley ; Hope A. Ishii ; Jeffrey J. Gillis-Davis 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2014
卷号：111
期号：5
页码：1732-1735
DOI：10.1073/pnas.1320115111
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：The solar wind (SW), composed of predominantly [~]1-keV H+ ions, produces amorphous rims up to [~]150 nm thick on the surfaces of minerals exposed in space. Silicates with amorphous rims are observed on interplanetary dust particles and on lunar and asteroid soil regolith grains. Implanted H+ may react with oxygen in the minerals to form trace amounts of hydroxyl (-OH) and/or water (H2O). Previous studies have detected hydroxyl in lunar soils, but its chemical state, physical location in the soils, and source(s) are debated. If -OH or H2O is generated in rims on silicate grains, there are important implications for the origins of water in the solar system and other astrophysical environments. By exploiting the high spatial resolution of transmission electron microscopy and valence electron energy-loss spectroscopy, we detect water sealed in vesicles within amorphous rims produced by SW irradiation of silicate mineral grains on the exterior surfaces of interplanetary dust particles. Our findings establish that water is a byproduct of SW space weathering. We conclude, on the basis of the pervasiveness of the SW and silicate materials, that the production of radiolytic SW water on airless bodies is a ubiquitous process throughout the solar system.
关键词：solar wind radiolysis ; prebiotic water ; cosmic dust ; astrobiology ; aberration-corrected scanning transmission electron microscopy