期刊名称:Proceedings of the National Academy of Sciences
印刷版ISSN:0027-8424
电子版ISSN:1091-6490
出版年度:2012
卷号:109
期号:45
页码:18306-18311
DOI:10.1073/pnas.1207475109
语种:English
出版社:The National Academy of Sciences of the United States of America
摘要:Chondritic meteorites are considered the most primitive remnants of planetesimals from the early Solar System. As undifferentiated objects, they also display widespread evidence of water-rock interaction on the parent body. Understanding this history has implications for the formation of planetary bodies, the delivery of water to the inner Solar System, and the formation of prebiotic molecules. The timescales of water-rock reactions in these early objects, however, are largely unknown. Here, we report evidence for short-lived water-rock reactions in the highly metamorphosed ordinary chondrite breccia Villalbeto de la Pena (L6). An exotic clast (d = 2cm) has coexisting variations in feldspar composition and oxygen isotope ratios that can only result from hydrothermal conditions. The profiles were modeled at T = 800 {degrees}C and P(H2O) = 1 bar using modified grain-boundary diffusion parameters for oxygen self-diffusion and reaction rates of NaSiCa-1Al-1 exchange in a fumarole. The geochemical data are consistent with hydrothermal activity on the parent body lasting only 1-10 y. This result has wide-ranging implications for the geological history of chondritic asteroids.