文章基本信息

标题：Functional Conducting Polymers via Thiol-ene Chemistry
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作者：Kathleen E. Feldman ; David C. Martin
期刊名称：Biosensors
电子版ISSN：2079-6374
出版年度：2012
卷号：2
期号：3
页码：305-317
DOI：10.3390/bios2030305
语种：English
出版社：MDPI Publishing
摘要：We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.
关键词：conducting polymer; thiol-ene; ProDOT; functionalization