文章基本信息

标题：Structure of the floating water bridge and water in an electric field
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作者：Lawrie B. Skinner ; Chris J. Benmore ; Badri Shyam 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2012
卷号：109
期号：41
页码：16463-16468
DOI：10.1073/pnas.1210732109
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：The floating water bridge phenomenon is a freestanding rope-shaped connection of pure liquid water, formed under the influence of a high potential difference (approximately 15 kV). Several recent spectroscopic, optical, and neutron scattering studies have suggested that the origin of the bridge is associated with the formation of anisotropic chains of water molecules in the liquid. In this work, high energy X-ray diffraction experiments have been performed on a series of floating water bridges as a function of applied voltage, bridge length, and position within the bridge. The two-dimensional X-ray scattering data showed no direction-dependence, indicating that the bulk water molecules do not exhibit any significant preferred orientation along the electric field. The only structural changes observed were those due to heating, and these effects were found to be the same as for bulk water. These X-ray scattering measurements are supported by molecular dynamics (MD) simulations which were performed under electric fields of 106 V/m and 109 V/m. Directional structure factor calculations were made from these simulations parallel and perpendicular to the E-field. The 106 V/m model showed no significant directional-dependence (anisotropy) in the structure factors. The 109 V/m model however, contained molecules aligned by the E-field, and had significant structural anisotropy.
关键词：water electric field ; pair distribution function ; temperature dependence ; high voltage