The main objective of research in this study is definition, extraction and evaluation of elements, consisting natural complex within the area of Obrenovac Municipality. An evaluation has been performed regarding mentioned, as one of main factors for positioning and environmental development of economy and settlements. In order to rationally use the environment for agriculture, development and tourism an partial and synthetic evaluation was performed on separate natural complex components (geology, geomorphology, climate, hydrography, pedology and biogeography characteristics), and their influence as geopotential for the development of examined area.