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  • 标题:Stochastic Model of Unimolecular Reactions and the RRKM Theory
  • 本地全文:下载
  • 作者:S. H. Lin ; K. H. Lau ; W. Richardson
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1972
  • 卷号:69
  • 期号:10
  • 页码:2778-2782
  • DOI:10.1073/pnas.69.10.2778
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:A stochastic model of unimolecular reactions has been adopted for investigation of the validity and limitation of the RRKM theory. The error caused by the steady-state approximation for distribution of energized molecules is small, while the assumption of the internal energy equilibration of energized molecules might cause serious errors for reactions of low activation energies.
  • 关键词:steady-state approximation ; energized molecules
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