文章基本信息

标题：Proton Magnetic Resonance Reveals High-Spin Iron (II) in Ferrous Cytochrome P450cam from Pseudomonas putida
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作者：Regula M. Keller ; Kurt Wüthrich ; Peter G. Debrunner 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：1972
卷号：69
期号：8
页码：2073-2075
DOI：10.1073/pnas.69.8.2073
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：High-resolution proton nuclear magnetic resonance spectra were studied in D(+)-camphor-saturated solutions of ferric and ferrous cytochrome P450cam from Pseudomonas putida, and of the cyanide complex of ferric P450cam. In all these compounds several hyperfineshifted resonances of the heme group could be detected. In the ferrous protein, these resonance lines, which exhibit a Curie-type temperature dependence in the range of 5-28{degrees
关键词：ferric and ferrous cytochrome P450_cam ; hyperfine shifts ; heme proteins