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  • 标题:Prebiotic Synthesis of Hydrophobic and Protein Amino Acids
  • 本地全文:下载
  • 作者:David Ring ; Yecheskel Wolman ; Nadav Friedmann
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1972
  • 卷号:69
  • 期号:3
  • 页码:765-768
  • DOI:10.1073/pnas.69.3.765
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:The formation of amino acids by the action of electric discharges on a mixture of methane, nitrogen, and water with traces of ammonia was studied in detail. The presence of glycine, alanine, [α]-amino-n-butyric acid, [α]-aminoisobutyric acid, valine, norvaline, isovaline, leucine, isoleucine, alloisoleucine, norleucine, proline, aspartic acid, glutamic acid, serine, threonine, allothreonine, [α]-hydroxy-{gamma}-aminobutyric acid, and [α],{gamma}-diaminobutyric acid was confirmed by ion-exchange chromatography and gas chromatography-mass spectrometry. All of the primary [α]-amino acids found in the Murchison Meteorite have been synthesized by this electric discharge experiment.
  • 关键词:electric-discharge synthesis ; gas chromatography-mass spectrometry ; amino-acid analyzer
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