文章基本信息

标题：The Crystal and Molecular Structure of an Intermolecular Complex between Riboflavin and an Adenosine Derivative
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作者：Donald Voet ; Alexander Rich
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：1971
卷号：68
期号：6
页码：1151-1156
DOI：10.1073/pnas.68.6.1151
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：Riboflavin and the adenosine derivative 5'-bromo-5'-deoxyadenosine form a crystalline 1:1 intermolecular complex, the structure of which has been solved by x-ray diffraction analysis. The adenine ring is found to be joined by two hydrogen bonds to the uracillike end of the riboflavin isoalloxazine ring. In addition, the riboflavin and the adenosine molecules associate through the formation of stacks of alternating parallel adenine and isoalloxazine rings. These intermolecular associations are considered to be models for intramolecular association in the coenzyme flavin adenine dinucleotide (FAD), which contains both adenosine and riboflavin.
关键词：FAD ; x-ray diffraction ; Fourier ; hydrogen bonding ; ring stacking