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  • 标题:Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous
  • 本地全文:下载
  • 作者:F. R. Díaz-Alzamora ; M. A. del Valle ; C. M. Núñez
  • 期刊名称:International Journal of Polymer Science
  • 印刷版ISSN:1687-9422
  • 电子版ISSN:1687-9430
  • 出版年度:2009
  • 卷号:2009
  • DOI:10.1155/2009/974307
  • 出版社:Hindawi Publishing Corporation
  • 摘要:A synthetic method based on the postfunctionalization of a reactive homopolymer precursor, which allows for the preparation of different copolymers derived from poly(3-alkylthiophene), was studied. Although these groups decrease the solubility of the resultant material, they enable controlling the degree of substitution to obtain a material with improved spectroscopic (absorption and emission) properties making them useful for the fabrication of electronic devices, for example, solar cells and light-emitting diodes. Furthermore, a comparative study of two halogenated (Cl and Br) reactive poly(3-ω-haloalkyl)thiophenes was carried out.
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