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标题：Nation-wide estimation of groundwater redox conditions and nitrate concentrations through machine learning
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作者：Lukas Knoll ; Lutz Breuer ; Martin Bach 等
期刊名称：Environmental Research Letters
印刷版ISSN：1748-9326
电子版ISSN：1748-9326
出版年度：2020
卷号：15
期号：6
页码：64004
DOI：10.1088/1748-9326/ab7d5c
出版社：IOP Publishing Ltd
摘要：The protection of water resources and development of mitigation strategies require large-scale information on water pollution such as nitrate. Machine learning techniques like random forest (RF) have proven their worth for estimating groundwater quality based on spatial environmental predictors. We investigate the potential of RF and quantile random forest (QRF) to estimate redox conditions and nitrate concentration in groundwater (1 km × 1 km resolution) using the European Water Framework Directive groundwater monitoring network as well as spatial environmental information available throughout Germany. The RF model for nitrate achieves a good predictive performance with an R2 of 0.52. Dominant predictors are the redox conditions in the groundwater body, hydrogeological units and the percentage of arable land. An uncertainty assessment using QRF shows rather large uncertainties with a mean prediction interval (MPI) of 53.0 mg l-1. This study represents the first nation-wide data-driven assessment of the spatial distribution of groundwater nitrate concentrations for Germany.
关键词：groundwater quality; large-scale; nitrate pollution; random forest; redox conditions; uncertainty