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标题：Synthesis and characterization of Cu-X/γ-Al2O3 catalyst by intermittent microwave irradiation for hydrogen generation from dimethyl ether steam reforming
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作者：Shilin Huang ; Juan Li ; Chang-Feng Yan 等
期刊名称：Chemical Industry and Chemical Engineering Quarterly
印刷版ISSN：1451-9372
出版年度：2018
卷号：24
期号：2
页码：169-178
DOI：10.2298/CICEQ160203029H
出版社：Association of the Chemical Engineers
摘要：A series of Cu-X/γ-Al2O3 (X = Fe, Co, Ni) catalysts were synthesized by a rapid intermittent microwave irradiation method for hydrogen generation from dimethyl ether steam reforming. Different parameters, such as the promoters of X (X = Fe, Co, Ni), microwave irradiation procedure and the ratio of metal to γ-Al2O3, were investigated. The results show that 2Cu-Fe/72γ-Al2O3 has the best performance, for which the agglomeration is prevented, CuO is well dispersed and the catalytic activity is improved. Promoter iron oxide in 2Cu-Fe/9γ-Al2O3 facilitates the watergas shift reaction, which lead to an increase in the conversion of CO to CO2 and hydrogen yield. Particularly, the 2Cu-Fe/72γ-Al2O3 catalyst, with the best molar ratio of metal to γ-Al2O3, shows a dimethyl ether conversion of >99% and a hydrogen yield of >98% and produces the lowest CO content of 1.4%, indicating that the synergism between dimethyl ether hydrolysis and methanol reforming requires an appropriate balance between the metallic Cu-Fe and the acid γ-Al2O3. The intermittent microwave irradiation technique provides a simple but effective method of the Cu-Fe/γ-Al2O3 synthesis with a good catalyst performance for the dimethyl ether steam reforming.
关键词：hydrogen generation; dimethyl ether; intermittent microwave; catalytic steam reforming