文章基本信息

标题：Study of gadolinium substitution effects in hexagonal yttrium manganite YMnO3
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作者：Dovydas Karoblis ; Aleksej Zarkov ; Edita Garskaite 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2021
卷号：11
期号：1
页码：2875
DOI：10.1038/s41598-021-82621-6
出版社：Springer Nature
摘要：Abstract In the present work, gadolinium substitution effects on the properties of yttrium manganite Y x Gd 1−x Mn 0.97 Fe 0.03 O 3 (x from 0 to 1 with a step of 0.2) synthesized by an aqueous sol–gel method have been investigated. Partial substitution of Mn 3 by 57 Fe 3 in the manganite was also performed in order to investigate deeper the structural properties of synthesized compounds applying Mössbauer spectroscopy. It was demonstrated that substitution of Y 3 by Gd 3 ions leads to the changes of structural, magnetic and morphological properties of investigated system. The crystal structure gradually transformed from hexagonal to orthorhombic with an increase of Gd 3 content in the crystal lattice. The mixed phase was obtained when x = 0.6, whereas other compounds were determined to be monophasic. Magnetization measurements revealed paramagnetic behavior of all specimens, however magnetization values were found to be dependent on chemical composition of the samples. Solid solutions with orthorhombic structure revealed higher magnetization values compared to those of hexagonal samples. The highest magnetization was observed for pure GdMn 0.97 Fe 0.03 O 3 . Structural properties were investigated by powder X-ray diffraction, Mössbauer, FTIR and Raman spectroscopies. Morphological features of the synthesized specimens were studied by scanning electron microscopy (SEM).
其他摘要：Abstract In the present work, gadolinium substitution effects on the properties of yttrium manganite Y x Gd 1−x Mn 0.97 Fe 0.03 O 3 (x from 0 to 1 with a step of 0.2) synthesized by an aqueous sol–gel method have been investigated. Partial substitution of Mn 3 by 57 Fe 3 in the manganite was also performed in order to investigate deeper the structural properties of synthesized compounds applying Mössbauer spectroscopy. It was demonstrated that substitution of Y 3 by Gd 3 ions leads to the changes of structural, magnetic and morphological properties of investigated system. The crystal structure gradually transformed from hexagonal to orthorhombic with an increase of Gd 3 content in the crystal lattice. The mixed phase was obtained when x = 0.6, whereas other compounds were determined to be monophasic. Magnetization measurements revealed paramagnetic behavior of all specimens, however magnetization values were found to be dependent on chemical composition of the samples. Solid solutions with orthorhombic structure revealed higher magnetization values compared to those of hexagonal samples. The highest magnetization was observed for pure GdMn 0.97 Fe 0.03 O 3 . Structural properties were investigated by powder X-ray diffraction, Mössbauer, FTIR and Raman spectroscopies. Morphological features of the synthesized specimens were studied by scanning electron microscopy (SEM).