文章基本信息

标题：Oxidation of Benzyl Alcohol Compounds in the Presence of Carbon Hybrid Supported Platinum Nanoparticles (Pt@CHs) in Oxygen Atmosphere
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作者：Haydar Göksu ; Hakan Burhan ; Sibel Demiroğlu Mustafov 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2020
卷号：10
期号：1
页码：1-8
DOI：10.1038/s41598-020-62400-5
出版社：Springer Nature
摘要：A novel catalyst which carbon hybrid supported platinum nanoparticles were synthesized by our group for the oxidation of benzyl alcohol derivatives. In this study, this catalyst was utilized for the oxidation of benzyl alcohol derivatives to benzaldehyde compounds in aqueous toluene at 80 °C. The benzaldehyde derivatives were synthesized in high yields and mild conditions in the presence of the catalyst by the developed method. Additionally, the prepared nanoparticles have been characterized by Transmission Electron Microscopy (TEM), the high-resolution electron micrograph (HR-TEM), X-ray Photoelectron Spectroscopy (XPS), and X-ray Diffraction (XRD). The mean particle size of the nanoparticles determined by the XRD technique was found to be 2.83 nm in parallel with TEM analysis. TEM analysis also indicated that the Pt nanoparticles were evenly dispersed on the support material. Finally, the Pt@CHs catalyst was shown also stable and reusable for the oxidation reaction, providing ≤95% conversion after its 3rd consecutive use in the oxidation reaction of various compounds.