文章基本信息

标题：Development of the N-Doped Cu-Carbon Composite as a Novel Catalyst for the Removal Reactive Black 5
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作者：Nargish Jahan Ara ; Mohammad Farhadur Rahman ; Zubair Hasan 等
期刊名称：Open Journal of Applied Sciences
印刷版ISSN：2165-3917
电子版ISSN：2165-3925
出版年度：2020
卷号：10
期号：7
页码：432-443
DOI：10.4236/ojapps.2020.107030
出版社：Scientific Research Publishing
摘要：In this study, two Cu-based catalysts with and without N doped carbon matrix, named N-Cu/CuO/C and Cu/CuO were synthesized via calcination of melamine-cupper acetate complex and cupper acetate at 500°C under an inert atmosphere. The catalysts were characterized by X-ray powder diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM), and CHNS elemental analyzer. The catalytic activity of both catalysts was evaluated through the NaBH4 associated reduction of commercial textile dye named reactive black 5 (RB5). The kinetics of the reduction of reactive black 5 was also described by the pseudo-first-order kinetic equation. For the studied reduction, N-Cu/CuO/C exhibited enhanced catalytic activity both in conversion and kinetics (97% conv. in 315 sec) compared to that of by Cu/CuO/C (25% conv. in 1500 sec). Besides, N-Cu/CuO/C also demonstrated good reusability up to four consecutive cycles.
关键词：Catalytic Reduction;Reactive Black 5;Non-Noble Metal Carbon Compo-sites;Calcinations