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  • 标题:Catalytic Dehydrogenation of Methylcyclohexane by Pt Nanoparticles Supported on Nitrogen doped Carbon
  • 本地全文:下载
  • 作者:Jian Wang ; Shiguang Fan ; Xuan Xu
  • 期刊名称:E3S Web of Conferences
  • 印刷版ISSN:2267-1242
  • 电子版ISSN:2267-1242
  • 出版年度:2020
  • 卷号:194
  • 页码:1030-1033
  • DOI:10.1051/e3sconf/202019401030
  • 出版社:EDP Sciences
  • 摘要:Pt nanoparticles supported on nitrogen doped carbon (Pt/CN) catalysts with different surface areas were obtained and characterized by transmission electron microscope (TEM) and brunner-emmet-teller (BET). The characterized results showed that Pt nanoparticles dispersed uniformly on the support surface, and the surface area of the Pt/CN catalyst increased with the increase of annealing temperature. Subsequently, the catalytic performance of Pt/CN catalysts for methylcyclohexane dehydrogenation was studied. The activity of Pt/CN catalysts in methylcyclohexane dehydrogenation increased with the increase of the surface area, Pt/CN-1000 catalyst has the largest surface area and the highest catalytic activity, with the methylcyclohexane conversion of 99% and the TOF value of 424.78 h -1 at 180 ℃ for 150 minutes.
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