文章基本信息

标题：Formal Aerobic Oxidative Cross-Coupling of Benzofuranones with Azo Compounds Using Pd-μ-hydroxo Complex
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作者：Rikako Ohnishi ; Masumi Sugawara ; Tetsuya Ezawa 等
期刊名称：Chemical and Pharmaceutical Bulletin
印刷版ISSN：0009-2363
电子版ISSN：1347-5223
出版年度：2020
卷号：68
期号：9
页码：895-898
DOI：10.1248/cpb.c20-00359
出版社：The Pharmaceutical Society of Japan
摘要：We have developed a catalytic aerobic oxidative dimerization reaction of benzofuranones using a Pd(II)-µ-hydroxo complex.Radical-radical cross-coupling of the resulting dimers with azo compounds enabled the one-pot synthesis of structurally congested benzofuranones having two distinct vicinal all-carbon quaternary centers.
关键词：palladium;molecular oxygen;radical;oxidative cross-coupling