文章基本信息

标题：Calibrated cryo-cell UV-LA-ICPMS elemental concentrations from the NGRIP ice core reveal abrupt, sub-annual variability in dust across the GI-21.2 interstadial period
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作者：Damiano Della Lunga ; Wolfgang Müller ; Sune Olander Rasmussen 等
期刊名称：The Cryosphere
印刷版ISSN：1994-0416
电子版ISSN：1994-0424
出版年度：2017
卷号：11
期号：3
页码：1297-1309
DOI：10.5194/tc-11-1297-2017
出版社：Copernicus Publications
摘要：Several abrupt shifts from periods of extreme cold (Greenland stadials, GS) to relatively warmer conditions (Greenland interstadials, GI) called Dansgaard–Oeschger events are recorded in the Greenland ice cores. Using cryo-cell UV-laser-ablation inductively coupled-plasma mass spectrometry (UV-LA-ICPMS), we analysed a 2.85 m NGRIP ice core section (2691.50–2688.65 m depth, age interval 84.86–85.09 ka b2k, thus covering ∼  230 years) across the transitions of GI-21.2, a short-lived interstadial prior to interstadial GI-21.1. GI-21.2 is a ∼  100-year long period with δ18O values 3–4 ‰ higher than the following ∼  200 years of stadial conditions (GS-21.2), which precede the major GI-21.1 warming. We report concentrations of major elements indicative of dust and/or sea salt (Na, Fe, Al, Ca, Mg) at a spatial resolution of ∼  200 µm, while maintaining detection limits in the low-ppb range, thereby achieving sub-annual time resolution even in deep NGRIP ice. We present an improved external calibration and quantification procedure using a set of five ice standards made from aqueous (international) standard solutions. Our results show that element concentrations decrease drastically (more than 10-fold) at the warming onset of GI-21.2 at the scale of a single year, followed by relatively low concentrations characterizing the interstadial part before gradually reaching again typical stadial values.