文章基本信息

标题：Tunable photoluminescence properties of selenium nanoparticles: biogenic versus chemogenic synthesis
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作者：Elena Piacenza ; Alessandro Presentato ; Belinda Heyne 等
期刊名称：Nanophotonics
印刷版ISSN：2192-8606
电子版ISSN：2192-8614
出版年度：2020
卷号：-1
期号：ahead-of-print
页码：1-14
DOI：10.1515/nanoph-2020-0239
出版社：Walter de Gruyter GmbH
摘要：Various technological and biomedical applications rely on the ability of materials to emit light (photoluminescence [PL]), and, among them, metal nanoparticles (NPs) and semi-conductor Quantum Dots (QDs) represent ideal candidates as sensing probes and imaging tools, portraying better PL features than conventional organic dyes. However, the knowledge of PL behavior of semiconductor NPs – i.e., selenium; SeNPs – is still in its infancy, especially for those synthesized by microorganisms. Considering the essential role played by biogenic SeNPs as antimicrobial, anticancer, and antioxidant agents, or food supplements, their PL properties must be explored to take full advantage of them as eco-friendly and versatile tools. Here, PL features of SeNPs produced by the Se-tolerant Stenotrophomonas maltophilia SeITE02 strain, compared with chemogenic ones, are investigated, highlighting the PL dependency on the NP size. Indeed, PL emission shifted from indigo-blue (emission wavelength λ em 400–450 nm) to green-yellow ( λ em 480–570 nm) and orange-red ( λ em 580–700 nm) for small (ca. 50 nm) and big (ca. 100 nm) SeNPs respectively, revealing the versatility of an environmental bacterial isolate to synthesize diverse PL probes. Besides, biogenic SeNPs show PL lifetime comparable to those of the most used fluorophores, supporting their potential application as markers for (bio)imaging.
关键词：biogenic selenium nanoparticles ; fluorescence ; photoluminescence ; semiconductor nanoparticles ; stenotrophomonas