文章基本信息

标题：Enhancing the durable performance of LiMn2O4 at high-rate and elevated temperature by nickel-magnesium dual doping
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作者：Yue Yu ; Junming Guo ; Mingwu Xiang 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2019
卷号：9
期号：1
页码：1-9
DOI：10.1038/s41598-019-53494-7
出版社：Springer Nature
摘要：Various nickel and magnesium dual-doped LiNi x Mg 0.08 Mn 1.92-x O 4 (x ≤ 0.15) were synthesized via a modified solid-state combustion method. All as-prepared samples show typical spinel phase with a well-defined polyhedron morphology. The Ni-Mg dual-doping obviously decreases the lattice parameter that gives rise to the lattice contraction. Owing to the synergistic merits of metal ions co-doping, the optimized LiNi 0.03 Mg 0.08 Mn 1.89 O 4 delivers high initial capacity of 115.9 and 92.9 mAh·g -1 , whilst retains 77.1 and 69.7 mAh·g -1 after 1000 cycles at 1 C and high current rate of 20 C, respectively. Even at 10 C and 55 °C, the LiNi 0.03 Mg 0.08 Mn 1.89 O 4 also has a discharge capacity of 92.2 mAh·g -1 and endures 500 cycles long-term life. Such excellent results are contributed to the fast Li + diffusion and robust structure stability. The anatomical analysis of the 1000 long-cycled LiNi 0.03 Mg 0.08 Mn 1.89 O 4 electrode further demonstrates the stable spinel structure via the mitigation of Jahn-Teller effect. Hence, the Ni-Mg co-doping can be a potential strategy to improve the high-rate capability and long cycle properties of cathode materials.