文章基本信息

标题：Multicomponent reactions (MCRs) of acetylenic compounds with isocyanides or triphenylphosphine–A Mini review
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作者：M. Ghazvini ; M. Ghazvini ; A. S. Shahvelayati 等
期刊名称：Journal of Materials and Environmental Science
印刷版ISSN：2028-2508
出版年度：2018
卷号：9
期号：11
页码：3049-3058
出版社：University of Mohammed Premier Oujda
摘要：Acetylenic esters such as dimethylacetylenedicarboxylat (DMAD), diethyl acetylenedicarboxylat (DEAD) and alkyl propiolates are esters in which the ester groups are conjugated with a C-C triple bond. As such, these molecules are highly electrophilic, and widely employed as a dienophile in cycloaddition reactions. They have been used in muliticomponent reactions in the presence of nucleophilic compounds such as Isocyanides, Isoquinoline, Quinoline, Triphenylphosphine, trialkyl (aryl) phosphites and NH-acidic or OH-acidic compounds. This review mainly focuses on the research work reported in the scientific literature on the reaction this compounds with Isocyanides and Triphenylphosphine.
关键词：Dimethyl acetylenedicarboxylate;✓ Isocyanids;✓ Triphenylphosphine;✓ Diethyl acetylenedicarboxylate;✓ Alkyl propiolates