文章基本信息

标题：Synthesis and Crystal Structure of the Energetic Compound [BAP(NO3) (ClO4)]
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作者：Fulei Gao ; Weixiao Liu ; Yongfei Pan 等
期刊名称：IOP Conference Series: Earth and Environmental Science
印刷版ISSN：1755-1307
电子版ISSN：1755-1315
出版年度：2019
卷号：252
期号：2
页码：1-5
DOI：10.1088/1755-1315/252/2/022066
出版社：IOP Publishing
摘要：A novel azido amine compound of [BAP(NO₃) (ClO₄)] (BAP=N, N'-1,4-bis(2-azidoethyl)-piperazine) was synthesized for the first time. The structure of [BAP(NO₃) (ClO₄)] was characterized by elemental analysis and FT-IR spectroscopy. Single crystals of [BAP(NO₃) (ClO₄)] were obtained through slow evaporation of a saturated water solution. The crystal structure was determined by X-ray single crystal diffraction and the crystallographic data showed that the compound crystallizes in the triclinic space group P-1 with crystal parameters of a=6.4899(2) Å, b=11.2349(2) Å, c=12.1047(2) Å, α=105.524(2)°, β=91.065(2)°, γ=103.056(2)°, V=825.47(4) Å³, Z=2.