文章基本信息

标题：Magnesium Ethylenediamine Borohydride as Solid-State Electrolyte for Magnesium Batteries
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作者：Elsa Roedern ; Ruben-Simon Kühnel ; Arndt Remhof 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2017
卷号：7
期号：1
DOI：10.1038/srep46189
语种：English
出版社：Springer Nature
摘要：Solid-state magnesium ion conductors with exceptionally high ionic conductivity at low temperatures, 5 × 10(-8) Scm(-1) at 30 °C and 6 × 10(-5) Scm(-1) at 70 °C, are prepared by mechanochemical reaction of magnesium borohydride and ethylenediamine. The coordination complexes are crystalline, support cycling in a potential window of 1.2 V, and allow magnesium plating/stripping. While the electrochemical stability, limited by the ethylenediamine ligand, must be improved to reach competitive energy densities, our results demonstrate that partially chelated Mg(2+) complexes represent a promising platform for the development of an all-solid-state magnesium battery.