文章基本信息

标题：Phase transitions in disordered mesoporous solids
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作者：Daniel Schneider ; Daria Kondrashova ; Rustem Valiullin 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2017
卷号：7
期号：1
DOI：10.1038/s41598-017-07406-2
语种：English
出版社：Springer Nature
摘要：Fluids confined in mesoporous solids exhibit a wide range of physical behavior including rich phase equilibria. While a notable progress in their understanding has been achieved for fluids in materials with geometrically ordered pore systems, mesoporous solids with complex pore geometries still remain a topic of active research. In this work we study phase transitions occurring in statistically disordered linear chains of pores with different pore sizes. By considering, quite generally, two phase change mechanisms, nucleation and phase growth, occurring simultaneously we obtain the boundary transitions and the scanning curves resulting upon reversing the sign of the evolution of the chemical potential at different points along the main transition branches. The results obtained are found to reproduces the key experimental observations, including the emergence of hysteresis and the scanning behavior. By deriving the serial pore model isotherm we suggest a robust framework for reliable structural analysis of disordered mesoporous solids.