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  • 标题:Partially Oxidized Sub-10 nm MnO Nanocrystals with High Activity for Water Oxidation Catalysis
  • 本地全文:下载
  • 作者:Kyoungsuk Jin ; Arim Chu ; Jimin Park
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2015
  • 卷号:5
  • 期号:1
  • DOI:10.1038/srep10279
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:The oxygen evolution reaction (OER) is considered a major bottleneck in the overall water electrolysis process. In this work, highly active manganese oxide nano-catalysts were synthesized via hot injection. Facile surface treatment generated Mn(III) species on monodisperse 10 nm MnO nanocrystals (NCs). Size dependency of MnO NCs on OER activity was also investigated. Surprisingly, the partially oxidized MnO NCs only required 530 mV @ 5 mA cm−2 under near neutral conditions.
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