文章基本信息

标题：Ultrafine ferroferric oxide nanoparticles embedded into mesoporous carbon nanotubes for lithium ion batteries
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作者：Guo Gao ; Qiang Zhang ; Xin-Bing Cheng 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2015
卷号：5
期号：1
DOI：10.1038/srep17553
语种：English
出版社：Springer Nature
摘要：An effective one-pot hydrothermal method for in situ filling of multi-wall carbon nanotubes (CNT, diameter of 20–40 nm, length of 30–100 μm) with ultrafine ferroferric oxide (Fe₃O₄) nanoparticles (8–10 nm) has been demonstrated. The synthesized Fe₃O₄@CNT exhibited a mesoporous texture with a specific surface area of 109.4 m² g⁻¹. The loading of CNT, in terms of the weight ratio of Fe₃O₄ nanoparticles, can reach as high as 66.5 wt%. Compared to the conventional method of using a Al₂O₃ membrane as template to fill CNT with iron oxides nanoparticles, our strategy is facile, effective, low cost and easy to scale up to large scale production (~1.42 g per one-pot). When evaluated for lithium storage at 1.0 C (1 C = 928 mA g⁻¹), the mesoporous Fe₃O₄@CNT can retain at 358.9 mAh g⁻¹ after 60 cycles. Even when cycled at high rate of 20 C, high capacity of 275.2 mAh g⁻¹ could still be achieved. At high rate (10 C) and long life cycling (500 cycles), the cells still exhibit a good capacity of 137.5 mAhg⁻¹.