文章基本信息

标题：2 μm emission properties and nonresonant energy transfer of Er3+ and Ho3+ codoped silicate glasses
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作者：Ruijie Cao ; Yu Lu ; Ying Tian 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2016
卷号：6
期号：1
DOI：10.1038/srep37873
语种：English
出版社：Springer Nature
摘要：2.0 μm emission properties of Er(3+)/Ho(3+) codoped silicate glasses were investigated pumped by 980 nm LD. Absorption spectra were determined. Intense mid-infrared emissions near 2 μm are observed. The spectral components of the 2 μm fluorescence band were analyzed and an equivalent model of four-level system was proposed to describe broadband 2 μm emission. Low OH(-) absorption coefficient (0.23 cm(-1)), high fluorescence lifetime (2.95 ms) and large emission cross section (5.61 × 10(-21) cm(2)) corresponding to Ho(3+): (5)I7→(5)I8 transition were obtained from the prepared glass. Additionally, energy transfer efficiency from the Er(3+): (4)I13/2 to the Ho(3+): (5)I7 level can reach as high as 85.9% at 0.75 mol% Ho2O3 doping concentration. Energy transfer microscopic parameters (CDA) via the host-assisted spectral overlap function were also calculated to elucidate the observed 2 μm emissions in detail. Moreover, the rate equation model between Er(3+) and Ho(3+) ions was developed to elucidate 2 μm fluorescence behaviors with the change of Ho(3+) concentration. All results reveal that Er(3+)/Ho(3+) codoped silicate glass is a promising material for improving the Ho(3+) 2.0 μm fiber laser performance.