文章基本信息

标题：Novel Porphyrinic Porous Organic Frameworks for High Performance Separation of Small Hydrocarbons
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作者：Heping Ma ; Hao Ren ; Shuang Meng 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2013
卷号：3
期号：1
DOI：10.1038/srep02611
语种：English
出版社：Springer Nature
摘要：A series of Porphyrinic-CTF materials are synthesized under ionothermal condition with high surface areas (>3200 m²/g) and tunable pore sizes. The ZnP-CTFs exhibit high adsorption capacities and selectivity towards C₃H₈, and C₂H₆ over CH₄ as IAST prediction. Furthermore, we explore the utility of ZnP-CTF for gas chromatographic separation of the small hydrocarbons mixture based on their different van der waals interactions and polarizability. More importantly, the fast breakthrough test further proves that the ZnP-CTF-400 and ZnP-CTF-500 can separate the small hydrocarbons under kinetic dynamic conditions.