文章基本信息

标题：Emerging superconductivity hidden beneath charge-transfer insulators
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作者：Yoshiharu Krockenberger ; Hiroshi Irie ; Osamu Matsumoto 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2013
卷号：3
期号：1
DOI：10.1038/srep02235
语种：English
出版社：Springer Nature
摘要：In many of today's most interesting materials, strong interactions prevail upon the magnetic moments, the electrons, and the crystal lattice, forming strong links between these different aspects of the system. Particularly, in two-dimensional cuprates, where copper is either five- or six-fold coordinated, superconductivity is commonly induced by chemical doping which is deemed to be mandatory by destruction of long-range antiferromagnetic order of 3 d ⁹ Cu²⁺ moments. Here we show that superconductivity can be induced in Pr₂CuO₄, where copper is four-fold coordinated. We induced this novel quantum state of Pr₂CuO₄ by realizing pristine square-planar coordinated copper in the copper-oxygen planes, thus, resulting in critical superconducting temperatures even higher than by chemical doping. Our results demonstrate new degrees of freedom, i.e., coordination of copper, for the manipulation of magnetic and superconducting order parameters in quantum materials.