文章基本信息

标题：Parasitic amorphous on single-domain crystal: Structural observations of silicate glass-ceramics
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作者：Yoshihiro Takahashi ; Yoshiki Yamazaki ; Rie Ihara 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2013
卷号：3
期号：1
DOI：10.1038/srep01147
语种：English
出版社：Springer Nature
摘要：Glass-ceramics (GCs) are materials obtained from the crystallisation of functional phases in glass, and have a structure that the crystallised phase embedded in the glass matrix. Glass-forming oxides are commonly added to the functional phases to improve the stability of precursor glass; however, the issue of glass-ceramics permitting the presence of residual phases resulting from addition is required to be clarified. To elucidate this issue, we prepared ‘perfectly surface-crystallised’ GC consisting of fresnoite-type Sr₂TiSi₂O₈ from a non-stoichiometric glass and performed texture/morphology observations. Numerous SiO₂-rich binodal-like nanospheres (~10 nm) were parasitic on the fresnoite single-crystal domains. The parasitic texture is considered to form via the following process: (i) binodal-type phase separation into stoichiometric fresnoite (crystalline matrix) and SiO₂-rich phases (amorphous nanoparticles) and (ii) single-domain formation by surface crystallisation in the matrix. Furthermore, in terms of texture, the resulting GC differs from the GCs reported to date, i.e., inverse GC.