文章基本信息

标题：A Rationally Designed Nitrogen-Rich Metal-Organic Framework and Its Exceptionally High CO2 and H2 Uptake Capability
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作者：Xiao-Jun Wang ; Pei-Zhou Li ; Yifei Chen 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2013
卷号：3
期号：1
DOI：10.1038/srep01149
语种：English
出版社：Springer Nature
摘要：On the way towards a sustainable low-carbon future, the design and construction of chemical or physical adsorbents for CO₂ capture and clean energy storage are vital technology. The incorporation of accessible nitrogen-donor sites into the pore walls of porous adsorbents can dramatically affect the CO₂ uptake capacity and selectivity on account of the dipole-quadrupole interactions between the polarizable CO₂ molecule and the accessible nitrogen site. In the present work, a nitrogen-rich rth -type metal-organic framework (MOF) was constructed based on rational design and careful synthesis. The MOF presents exceptionally high uptake capacity not only for CO₂ but also for H₂, which is attributed to favorable interactions between the gas molecules and the nitrogen-rich triazole units of the MOF proved by both experimental measurements and theoretical molecular simulations.