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标题：Coupled ferroelectric polarization and magnetization in spinel FeCr2S4
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作者：L. Lin ; H. X. Zhu ; X. M. Jiang 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2015
卷号：4
期号：1
DOI：10.1038/srep06530
语种：English
出版社：Springer Nature
摘要：One of the core issues for multiferroicity is the strongly coupled ferroelectric polarization and magnetization, while so far most multiferroics have antiferromagnetic order with nearly zero magnetization. Magnetic spinel compounds with ferrimagnetic order may be alternative candidates offering large magnetization when ferroelectricity can be activated simultaneously. In this work, we investigate the ferroelectricity and magnetism of spinel FeCr₂S₄ in which the Fe²⁺ sublattice and Cr³⁺ sublattice are coupled in antiparallel alignment. Well defined ferroelectric transitions below the Fe²⁺ orbital ordering termperature T_oo = 8.5 K are demonstrated. The ferroelectric polarization has two components. One component arises mainly from the noncollinear conical spin order associated with the spin-orbit coupling, which is thus magnetic field sensitive. The other is probably attributed to the Jahn-Teller distortion induced lattice symmetry breaking, occuring below the orbital ordering of Fe²⁺. Furthermore, the coupled ferroelectric polarization and magnetization in response to magnetic field are observed. The present work suggests that spinel FeCr₂S₄ is a multiferroic offering both ferroelectricity and ferrimagnetism with large net magnetization.