文章基本信息

标题：Nanoporous CuS with excellent photocatalytic property
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作者：Wence Xu ; Shengli Zhu ; Yanqin Liang 等
期刊名称：Scientific Reports
电子版ISSN：2045-2322
出版年度：2016
卷号：5
期号：1
DOI：10.1038/srep18125
语种：English
出版社：Springer Nature
摘要：We present the rational synthesis of nanoporous CuS for the first time by chemical dealloying method. The morphologies of the CuS catalysts are controlled by the composition of the original amorphous alloys. Nanoporous Cu₂S is firstly formed during the chemical dealloying process, and then the Cu₂S transforms into CuS. The nanoporous CuS exhibits excellent photocatalytic activity for the degradation of the methylene blue (MB), methyl orange (MO) and rhodamine B (RhB). The excellent photocatalytic activity of the nanoporous CuS is mainly attributed to the large specific surface area, high adsorbing capacity of dyes and low recombination of the photo generated electrons and holes. In the photo degradation process, both chemical and photo generated hydroxyl radicals are generated. The hydroxyl radicals are favor in the oxidation of the dye molecules. The present modified dealloying method may be extended for the preparation of other porous metal sulfide nanostructures.