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  • 标题:Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
  • 本地全文:下载
  • 作者:Cong Ye ; Yanbin Zhang ; Aishun Ding
  • 期刊名称:Scientific Reports
  • 电子版ISSN:2045-2322
  • 出版年度:2018
  • 卷号:8
  • 期号:1
  • 页码:2205
  • DOI:10.1038/s41598-018-20631-7
  • 语种:English
  • 出版社:Springer Nature
  • 摘要:We report herein a visible light sensitizer-catalyzed aerobic oxidation of thioethers, affording sulfoxides in good to excellent yields. The loading of the catalyst was as low as 0.1 mol%. The selectivity was excellent. Mechanism studies showed both singlet oxygen and superoxide radical anion were likely involved in this transformation.
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