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  • 标题:Origin of the emergent fragile-to-strong transition in supercooled water
  • 作者:Rui Shi ; John Russo ; Hajime Tanaka
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:2018
  • 卷号:115
  • 期号:38
  • 页码:9444-9449
  • DOI:10.1073/pnas.1807821115
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:Liquids can be broadly classified into two categories, fragile and strong ones, depending on how their dynamical properties change with temperature. The dynamics of a strong liquid obey the Arrhenius law, whereas the fragile one displays a super-Arrhenius law, with a much steeper slowing down upon cooling. Recently, however, it was discovered that many materials such as water, oxides, and metals do not obey this simple classification, apparently exhibiting a fragile-to-strong transition far above
  • 关键词:water’s anomalies ; structural origin ; two-state model ; fragile-to-strong transition ; dynamic heterogeneity
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