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  • 标题:Engineering Optical Activity of Semiconductor Nanocrystals via Ion Doping
  • 本地全文:下载
  • 作者:Nikita V. Tepliakov ; Anvar S. Baimuratov ; Yurii K. Gun’ko
  • 期刊名称:Nanophotonics
  • 印刷版ISSN:2192-8606
  • 电子版ISSN:2192-8614
  • 出版年度:2016
  • 卷号:5
  • 期号:4
  • 页码:573-578
  • DOI:10.1515/nanoph-2016-0034
  • 出版社:Walter de Gruyter GmbH
  • 摘要:

    Controlling the strength of enantioselective interaction of chiral inorganic nanoparticles with circularly polarized light is an intrinsically interesting subject of contemporary nanophotonics. This interaction is relatively weak, because the chirality scale of nanoparticles is much smaller than the optical wavelength. Here we theoretically demonstrate that ion doping provides a powerful tool of engineering and enhances optical activity of semiconductor nanocrystals. We show that by carefully positioning ionic impurities inside the nanocrystals, one can maximize the rotatory strengths of intraband optical transitions, and make them 100 times larger than the typical rotatory strengths of small chiral molecules.

  • 关键词:Ion doping ; chirality ; nanocrystals ; circular dichroism
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