文章基本信息

标题：A Fluorinated Cobalt(III) Porphyrin Complex for Hydroalkoxylation of Alkynes
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作者：Richiro Ushimaru ; Takuho Nishimura ; Toshiki Iwatsuki 等
期刊名称：Chemical and Pharmaceutical Bulletin
印刷版ISSN：0009-2363
电子版ISSN：1347-5223
出版年度：2017
卷号：65
期号：11
页码：1000-1003
DOI：10.1248/cpb.c17-00568
语种：English
出版社：The Pharmaceutical Society of Japan
摘要：

A fluorinated cobalt(III) porphyrin complex [Co(TPFPP)NTf₂·2C₂H₅OH, where TPFPP=5,10,15,20-tetrakis(pentafluorophenyl)porphyrin, Tf=CF₃SO₂] promotes hydroalkoxylation of alkynes to give acetals in good to excellent yields. The acetals can be directly functionalized with nucleophiles in a one-pot procedure.
关键词：hydroalkoxylation;acetal;alkyne;alcohol;cobalt;porphyrin