文章基本信息

标题：Chiral Organocatalyzed Intermolecular Rauhut–Currier Reaction of Nitroalkenes with Ethyl Allenoate
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作者：Shinobu Takizawa ; Makoto Sako ; Kenta Kishi 等
期刊名称：Chemical and Pharmaceutical Bulletin
印刷版ISSN：0009-2363
电子版ISSN：1347-5223
出版年度：2017
卷号：65
期号：11
页码：997-999
DOI：10.1248/cpb.c17-00554
语种：English
出版社：The Pharmaceutical Society of Japan
摘要：

An enantioselective intermolecular Rauhut–Currier (RC) reaction of nitroalkenes with ethyl allenoate has been established with quinidine-derived β-isocupreidine. The present RC reaction afforded α-functionalized allenoates 3 in up to 94% yield with 59% enantiomeric excess (ee).
关键词：Rauhut–Currier reaction;chiral organocatalysis;nitroalkene;α-functionalized allenoate