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  • 标题:Water structure-dependent charge transport in proteins
  • 本地全文:下载
  • 作者:P R Gascoyne ; R Pethig ; A Szent-Györgyi
  • 期刊名称:Proceedings of the National Academy of Sciences
  • 印刷版ISSN:0027-8424
  • 电子版ISSN:1091-6490
  • 出版年度:1981
  • 卷号:78
  • 期号:1
  • 页码:261-265
  • DOI:10.1073/pnas.78.1.261
  • 语种:English
  • 出版社:The National Academy of Sciences of the United States of America
  • 摘要:Dielectric and conductivity measurements are reported for bovine serum albumin as a function of hydration. Strong evidence is found for the existence of mobile charges whose short- and long-range hopping motion strongly depends on the physical state of the protein-bound water. These charges are considered to be protons. Insights into the nature of the electrical properties of protein-methylglyoxal complexes are provided, and the possibilities for correlated proton-electron motions are outlined.
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