文章基本信息

标题：The triplet state in bacterial photosynthesis: Possible mechanisms of the primary photo-act
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作者：Marion C. Thurnauer ; Joseph J. Katz ; James R. Norris 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：1975
卷号：72
期号：9
页码：3270-3274
DOI：10.1073/pnas.72.9.3270
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：In vitro and in vivo triplet state electron paramagnetic resonance (epr) spectra of bacteriochlorophylls (Bchls) show important differences in (a) electron spin polarization (esp), and (b) zero field splitting (ZFS) parameters. The unusual esp and ZFS properties of the observed in vivo triplet state are best interpreted as arising from a short-lived radical pair precursor (not directly observable by epr) formed in or with the special pair of bacteriochlorophyll molecules involved in the primary photo-act.
关键词：electron paramagnetic resonance ; electron spin polarization ; radical pair ; special pair