文章基本信息

标题：Molecular random tilings as glasses
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作者：Juan P. Garrahan ; Andrew Stannard ; Matthew O. Blunt 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2009
卷号：106
期号：36
页码：15209-15213
DOI：10.1073/pnas.0902443106
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：We have recently shown that p-terphenyl-3,5,3',5'-tetracarboxylic acid adsorbed on graphite self-assembles into a two-dimensional rhombus random tiling. This tiling is close to ideal, displaying long-range correlations punctuated by sparse localized tiling defects. In this article we explore the analogy between dynamic arrest in this type of random tilings and that of structural glasses. We show that the structural relaxation of these systems is via the propagation-reaction of tiling defects, giving rise to dynamic heterogeneity. We study the scaling properties of the dynamics and discuss connections with kinetically constrained models of glasses.
关键词：dimer coverings ; dynamic heterogeneity ; glass transition ; lozenge tilings