文章基本信息

标题：Dynamic combinatorial synthesis of a catenane based on donor–acceptor interactions in water
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作者：Ho Yu Au-Yeung ; G. Dan Pantoş ; Jeremy K. M. Sanders 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2009
卷号：106
期号：26
页码：10466-10470
DOI：10.1073/pnas.0809934106
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：A new type of neutral donor-acceptor [2]-catenane, containing both complementary units in the same ring was synthesized from a dynamic combinatorial library in water. The yield of the water soluble [2]-catenane is enhanced by increasing either building-block concentrations or ionic strength, or by the addition of an electron-rich template. NMR spectroscopy demonstrates that the template is intercalated between the 2 electron-deficient naphthalenediimide units of the catenane.
关键词：dynamic combinatorial chemistry ; molecular recognition