文章基本信息

标题：Using multimodal ligands to influence network topology in silver(I) coordination polymers
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作者：Neil S. Oxtoby ; Alexander J. Blake ; Neil R. Champness 等
期刊名称：Proceedings of the National Academy of Sciences
印刷版ISSN：0027-8424
电子版ISSN：1091-6490
出版年度：2002
卷号：99
期号：8
页码：4905-4910
DOI：10.1073/pnas.082647399
语种：English
出版社：The National Academy of Sciences of the United States of America
摘要：A range of Ag(I) one- and two-dimensional coordination frameworks has been prepared and structurally characterized by using the multimodal ligand 3,6-di-pyrazin-2-yl-(1,2,4,5)-tetrazine, which offers both monodentate and chelating binding sites. It is demonstrated that multimodal ligands can be used to prepare coordination frameworks with novel and unusual topologies and to influence the precise geometrical arrangement of both ligands and metal centers within such supramolecular arrays.
关键词：crystal engineering|supramolecular chemistry|tetrazine